The excessive atmospheric¹ carbon dioxide that is driving global climate change could be harnessed into a renewable energy technology that would be a win for both the environment and the economy. That is the lure² of artificial photosynthesis³ in which the electrochemical reduction of carbon dioxide is used to produce clean, green and sustainable fuels. However, finding a catalyst⁴ for reducing carbon dioxide that is highly selective and efficient has proven to be a huge scientific challenge. Meeting this challenge in the future should be easier thanks to new research results from Berkeley Lab. Peidong Yang, a chemist with Berkeley Lab's Materials Sciences Division, led a study in which bimetallic nanoparticles of gold and copper⁵ were used as the catalyst for the carbon dioxide reduction. The results experimentally revealed for the first time the critical influence of the electronic and geometric effects in the reduction reaction.

 

"Acting⁶ synergistically, the electronic and geometric effects dictate⁷ the binding⁸ strength for reaction intermediates and consequently the catalytic selectivity and efficiency in the electrochemical reduction of carbon dioxide," Yang says. "In the future, the design of carbon dioxide reduction catalysts⁹ with good activity and selectivity will require the careful balancing of these two effects as revealed in our study."

 

Yang, who also holds appointments with the University of California (UC) Berkeley and the Kavli Energy NanoSciences Institute at Berkeley, is a leading authority on nanoparticle phenomena¹⁰. His most recent research has focused on nanocatalysts fashioned from metal alloys¹¹ rather than a single metal such as gold, tin or copper.

 

Nanoscience expert Peidong Yang holds appointments with Berkeley Lab, UC Berkeley and the Kavli Energy NanoSciences Institute at Berkeley. (Photo by Roy Kaltschmidt)

 

"By alloying, we believe we can tune¹² the binding strength of intermediates on a catalyst surface to enhance the reaction kinetics for the carbon dioxide reduction," he says. "Nanoparticles provide an ideal platform for studying this effect because, through appropriate synthetic¹³ processes, we can access a wide range of compositions, sizes and shapes, allowing for a deeper understanding of catalyst performance through precise control of active sites."

 

In addition, Yang says, nanoparticle as catalysts have high surface-to-volume and surface-to-mass ratios that are advantageous¹⁴ for achieving high catalytic activity. For this new study, uniform gold-copper bimetallic nanoparticles with different compositions were assembled into ordered monolayers then observed during carbon dioxide reduction.

 

"The ordered monolayers served as a well-defined platform that enabled us to better understand their fundamental catalytic activity in carbon dioxide reduction," Yang says. "Based on our observations, the activity of the gold-copper bimetallic nanoparticles can be explained in terms of the electronic effect, in which the binding of intermediates can be tuned¹⁵ using different surface compositions, and the geometric effect, in which the local atomic arrangement at the active site allows the catalyst to deviate¹⁶ from the scaling relation."

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