Dendrites -- the microscopic¹, pin-like fibers² that cause rechargeable batteries to short circuit -- create fire hazards and can limit the ability of batteries to power our smart phones and store renewable energy for a rainy day. Now a new electrolyte for lithium batteries that's described in Nature Communications eliminates dendrites while also enabling batteries to be highly efficient and carry a large amount of electric current. Batteries using other dendrite-limiting solutions haven't been able to maintain both high efficiencies and current densities³.

 

"Our new electrolyte helps lithium batteries be more than 99 percent efficient and enables them to carry more than ten times more electric current per area than previous technologies," said physicist⁴ Ji-Guang "Jason" Zhang of the Department of Energy's Pacific Northwest National Laboratory. "This new discovery could kick-start the development of powerful and practical next-generation rechargeable batteries such as lithium-sulfur, lithium-air and lithium-metal batteries."

 

 

Most of the rechargeable batteries used today are lithium-ion batteries, which have two electrodes: one that's positively⁵ charged and contains lithium and another, negative one that's typically made of graphite. Electricity is generated when electrons flow through a wire that connects the two. To control the electrons, positively charged lithium atoms shuffle⁶ from one electrode to the other through another path: the electrolyte solution in which the electrodes sit. But graphite has a low energy storage capacity, limiting the amount of energy a lithium-ion battery can provide smart phones and electric vehicles.

 

When lithium-based rechargeable batteries were first developed in the 1970s, researchers used lithium for the negative electrode, which is also known as an anode. Lithium was chosen because it has ten times more energy storage capacity than graphite. Problem was, the lithium-carrying electrolyte reacted with the lithium anode. This caused microscopic lithium dendrites to grow and led the early batteries to fail.

 

Many have tweaked rechargeable batteries over the years in an attempt to resolve the dendrite problem. In the early 1990s, researchers switched to other materials such as graphite for the anode. More recently, scientists have also coated the anode with a protective layer, while others have created electrolyte additives⁷. Some solutions eliminated dendrites, but also resulted in impractical⁸ batteries with little power. Other methods only slowed, but didn't stop, the fiber's growth.

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