Groundbreaking work at two Department of Energy national laboratories has confirmed plutonium's magnetism¹, which scientists have long theorized but have never been able to experimentally observe. The advances that enabled the discovery hold great promise for materials, energy and computing² applications. Plutonium was first produced in 1940 and its unstable³ nucleus⁴ allows it to undergo fission⁵, making it useful for nuclear fuels as well as for nuclear weapons. Much less known, however, is that the electronic cloud surrounding the plutonium nucleus is equally unstable and makes plutonium the most electronically complex element in the periodic table, with intriguingly⁶ intricate properties for a simple elemental metal. 

 

While conventional theories have successfully explained plutonium's complex structural⁷ properties, they also predict that plutonium should order magnetically. This is in stark⁸ contrast with experiments, which had found no evidence for magnetic order in plutonium.

 

Finally, after seven decades, this scientific mystery on plutonium's "missing" magnetism has been resolved. Using neutron⁹ scattering¹⁰, researchers from the Department of Energy's Los Alamos and Oak Ridge¹¹ (ORNL) national laboratories have made the first direct measurements of a unique characteristic of plutonium's fluctuating magnetism. In a recent paper in the journal Science Advances, Marc Janoschek from Los Alamos, the paper's lead scientist, explains that plutonium is not devoid¹² of magnetism, but in fact its magnetism is just in a constant state of flux¹³, making it nearly impossible to detect.

 

"Plutonium sort of exists between two extremes in its electronic configuration--in what we call a quantum mechanical superposition," Janoschek said. "Think of the one extreme where the electrons are completely localized around the plutonium ion, which leads to a magnetic moment. But then the electrons go to the other extreme where they become delocalized and are no longer associated with the same ion anymore."

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