An efficient method to harvest low-grade waste heat as electricity may be possible using reversible ammonia batteries, according to Penn State engineers. "The use of waste heat for power production would allow additional electricity generation without any added consumption of fossil fuels," said Bruce E. Logan, Evan Pugh Professor and Kappe Professor of Environmental Engineering. "Thermally¹ regenerative batteries are a carbon-neutral way to store and convert waste heat into electricity with potentially lower cost than solid-state devices."

 

Low-grade waste heat is an artifact of many energy-generating methods. In automobiles², waste heat generated in winter is diverted to run the vehicle heating system, but in the summer, that same waste heat must be dissipated to the environment. Coal, nuclear and other power plants require high heat to produce electricity, but after producing electricity the excess waste heat is routed to cooling towers to dissipate. Many industrial sites, geothermal sources or solar generating plants also create low-grade heat that is wasted.

 

The researchers want to take this waste heat and capture it to produce more power. Other researchers have tried a variety of methods, but most produce too little power to be workable, or they cannot provide a continuous resource. Logan and his team are using a thermally regenerated³ ammonia-based battery that consists of copper⁴ electrodes with ammonia added only to the anolyte -- the electrolyte surrounding the anode.

 

"The battery will run until the reaction uses up the ammonia needed for complex formation in the electrolyte near the anode or depletes⁵ the copper ions in the electrolyte near the cathode," said Fang⁶ Zhang, postdoctoral fellow in environmental engineering. "Then the reaction stops."

 

This type of battery would be useless as a constant source of electricity if the reaction were not regenerative. Using low-grade waste heat from an outside source, the researchers distill⁷ ammonia from the effluent left in the battery anolyte and then recharge it into the original cathode chamber⁸ of the battery.

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