Usually, microelectronic devices are made of silicon¹ or similar semiconductors². Recently, the electronic properties of metal oxides have become quite interesting. These materials are more complex, yet offer a broader range of possibilities to tune³ their properties. An important breakthrough has now been achieved at the Vienna University of Technology: a two dimensional electron gas was created in strontium titanate. In a thin layer just below the surface electrons can move freely and occupy different quantum states. Strontium titanate is not only a potential future alternative to standard semiconductors, it could also exhibit interesting phenomena⁴, such as superconductivity, thermoelectricity（温差电学） or magnetic effects that do not occur in the materials that are used for today's electronic devices.

 

 

This project closely links theoretical calculations and experiments. Zhiming Wang from Professor Ulrike Diebold's research team was the leading experimentalist; some of the experimental work was done at the synchrotron（同步加速器） BESSY in Berlin. Zhicheng Zhong from Professor Karsten Held's group studied the material in computer simulations.

 

Not all of the atoms of strontium titanate are arranged in the same pattern: if the material is cut at a certain angle, the atoms of the surface layer form a structure, which is different from the structure in the bulk of the material. "Inside, every titanium atom has six neighbouring oxygen atoms, whereas the titanium atoms at the surface are only connected to four oxygen atoms each," says Ulrike Diebold. This is the reason for the remarkable⁵ chemical stability of the surface. Normally such materials are damaged if they come into contact with water or oxygen.

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