第十四章 红外分光光度法
红外线:infrared ray,IR
中红外吸收光谱:mid-infrared1 absorption spectrum,Mid-IR
远红外光谱:Far-IR
微波谱:microwave spectrum,MV
红外吸收光谱法:infrared spectroscopy
红外分光光度法:infrared spectrophotometry
振动形式:mode of vibration2
伸缩振动:stretching vibration
对称伸缩振动:symmetrical stretching vibration
不对称伸缩振动:asymmetrical stretching vibration
弯曲振动:bending vibration
变形振动:formation vibration
面内弯曲振动:in-plane bending vibration,β
剪式振动:scissoring vibration,δ
面内摇摆振动:rocking vibration,ρ
面外弯曲振动:out-of-plane bending vibration,γ
面外摇摆振动:wagging vibration,ω
蜷曲振动:twisting vibration ,τ
对称变形振动:symmetrical deformation3 vibration ,δs
不对称变形振动:asymmetrical deformation vibration, δas
特征吸收峰:charateristic avsorption band
特征频率:characteristic frequency
相关吸收峰:correlation absorption band
杂化影响:hybridization affect
环大小效应:ring size effect
吸收峰的强度:intensity of absorption band
环折叠振动:ring prckering vibration
第十五章 原子吸收分光光度法
原子光谱法:atomic spectroscopy
原子吸收分光光度法:atomic absorption spectrophotometry,AAS
原子发射分光光度法:atomic emmsion spectrophotometry,AES
原子荧光分光光度法:atomic fluorescence spectrophotometry,AFS
第十六章 核磁共振波谱法
核磁共振:nuclear magnetic resonance,NMR
核磁共振波谱:NMR spectrum
核磁共振波谱法:NMR spectroscopy
扫场:swept field
扫频:seept frequency
连续波核磁共振:continuous wave NMR,CW NMR
Fourier变换NMR:PFT-NMR,FT-NMR
二维核磁共振谱:2D-NMR
质子核磁共振谱:proton magnetic resonance spectrum,PMR
氢谱:1H-NMR
碳-13核磁共振谱:13C-NMR spectrum,13CNMR
自旋角动量:spin angular momentum
磁旋比:magnetogyric ratio
磁量子数:magnetic quantum number,m
进动:precession
弛豫历程:relaxation mechanism
局部抗磁屏蔽:local diamagnetic shielding
屏蔽常数:shielding constant
化学位移:chemical shift
国际纯粹与应用化学协会:IUPAC
磁各向异性:magnetic anisotropy
远程屏蔽效应:long range shielding effect
结面:nodal plane
自旋-自旋偶合:spin-spin coupling
自旋-自旋分裂:spin=spin splitting
单峰:singlet,s
双峰:doublet,d
三重峰:triplet,t
四重峰:quartet
五重峰:quintet
六重峰:sextet
偕偶:geminal coupling
邻偶:vicinal coupling
远程偶合:long range coupling
磁等价:magnetic eqivalence
自旋系统:spin system
一级光谱:first order spectrum
二级光谱(二级图谱):second order spectrum
C-H光谱:C-H correlated spectroscopy,C-H COSY
第十七章 质谱法
质谱分析法:mass spectrometry
质谱:mass spectrum,MS
棒图:bar graph
选择离子检测:selected ion monitoring ,SIM
直接进样:direct probe inlet ,DPI
接口:interface
气相色谱-质谱联用:gas chromatography-mass spectrometry,GC-MS
高效液相色谱-质谱联用:high performance liquid chromatography-mass spectrometry,HPLC-MS
电子轰击离子源:electron impact source,EI
离子峰:quasi-molecular ions
化学离子源:chemical ionization source,CI
场电离:field ionization,FI
场解析:field desorptiion,FD
快速原子轰击离子源:fast stom bombardment ,FAB
质量分析器:mass analyzer
磁质谱仪:magnetic-sector mass spectrometer
四极杆质谱仪(四极质谱仪):quadrupole mass spectrometer
原子质量单位:amu
离子丰度:ion abundance
相对丰度(相对强度):relative avundance
基峰:base peak
质量范围:mass range
分辨率:resolution
灵敏度:sensitivity
信噪比:S/N
分子离子:molecular ion
碎片离子:fragment ion
同位素离子:isotopic ion
亚稳离子:metastable ion
亚稳峰:metastable peak
母离子:paren ion
子离子:daughter
含奇数个电子的离子:odd electron
含偶数个电子的离子:even eletron,EE
均裂:homolytic cleavage
异裂(非均裂):heterolytic cleavage
半均裂:hemi-homolysis cleavage
重排:rearragement
分子量:MW
α-裂解:α-cleavage
第十八章 色谱分析法概论
色谱法(层析法):chromatography
固定相:stationary phase
流动相:mobile phase
超临界流体色谱法:SFC
高效毛细管电泳法:high performance capillary electroporesis,HPEC
气相色谱法:gas chromatography,GC
液相色谱法:liquid cromatography,LC
超临界流体色谱法:supercritical fluid chromatography,SFC
气-固色谱法:GSC
气-液色谱法:GLC
液-固色谱法:LSC
液-液色谱法:LLC
柱色谱法:column chromatography
填充柱:packed column
毛细管柱:capillary column
微填充柱:icrobore packed column
高效液相色谱法:high performance liquid chromatography,HPLC
平板色谱法:planar
平板色谱法:plane chromatography
纸色谱法:paper chromatography
薄层色谱法:thin layer chromatography,TLC
薄膜色谱法;thiin film chomatography
毛细管电泳法:capillary electrophoresis,CE
分配色谱法:partition chromatography
吸附色谱法:adsorpion chromaography
离子交换色谱法:ion exchange chromatography,IEC
空间排阻色谱法:steric exclusion chromatography,SEC
亲和色谱法:affinity chromatography
分配系数:distribution cofficient
狭义分配系数:partition coefficient
凝胶色谱法:gel chromatography
凝胶渗透色谱法:gel permeation chromatography,GPC
凝胶过滤色谱法:gel filtration chromatography,GFC
渗透系数:permeation coefficien;Kp
化学键合相色谱法:chemically bonded-phase chromatography
分配系数:distribution coefficient
靛菁绿:indocyanine
气相色谱-傅立叶变换红外光谱:GC-FTIR
第十九章 经典液相色谱法
薄层色谱法:TLC
吸附:adsorption
活化:activation
脱活性:deactivation
交联度:degree of cross linking
交换容量:exchange capacity
薄层板:thin layer plate
展开剂:developing solvent ,developer
临界胶束浓度:criticak micolle concentration ,CMC
相对比移值:relative Rf, Rr
分离度:resolution ,R
分离数:separation number,SN
煅石膏:Gypsum
羧甲基纤维素钠:CMC-Na
吸收光谱联用:TLC-UV
薄层色谱-荧光联用:TLC-F
薄层色谱-红外吸收光谱联用:TLC-IR
薄层色谱法:TLC-MS
纸色谱法:paper chromatography
上行展开:ascending development
下行法展开:descending development
双向展开:two dimensional develoooment
第二十章 气相色谱法
气相色谱法:gas chromatography
前延峰:leading peak
拖尾峰:tailing peak
对称因子:symmetry factor,fs
保留时间:retention time
保留体积:retention volume
死时间:dead time
调整保留时间:asjusted retention time
半峰宽:peak width at half height,W1/2 or Y1/2
峰宽:peak width,W
等温线:isotherm
理论塔板高度:height equivalent to atheoretical plate
化学键合相:chemically bonded phase
丁二酸二乙二醇聚酯:polydiethylene glycol succinate,PDEGS,DEGS
高分子多孔微球:GDX
苯乙烯:STY
乙基乙烯苯:EST
二乙烯苯:DVB
涂壁毛细管柱:wall coated open tubular column,WCOT
载体涂层毛细管柱:supprot coated open tubular column,SCOT
热导检测器:thermal conductivity detector,TCD
氢焰离子化检测器:hydrogen flame ionization detector,FID
电子捕获检测器:electron capture detector ,ECD
噪声:noise,N
漂移:drift,d
灵敏度:sensitivity
检测限(敏感度):detectability,D,M
分离度:resolution
归一化法:normalization method
外标法:external standardization
第二十一章 高效液相色谱法
高效液相色谱法:high performance liquid chromatography,HPLC
高速液相色谱法:high speed LC,HSLC
高压液相色谱法:high pressure LC,HPLC
高分辨液相色谱法:high resolution LC,HRLC
液固吸附色谱法(液固色谱法):liquid-solid adsorption chromatography,LSC
液液色谱法:liquid-liquid chromatography,LLC
正相:normal phase,NP
反相:reversed phase,RP
化学键合相色谱法:bonded phase chromatography,BPC
十八烷基:octadecylselyl,ODS
离子对色谱法:paired ion chromatography,PIC
反相离子对色谱法:RPIC
离子抑制色谱法:ion suppression chromatography,ISC
离子色谱法:ion chromatography,IC
手性色谱法:chiral chromatography,CC
环糊精色谱法:cyclodextrin chromatography,CDC
胶束色谱法:micellar chromatography,MC
亲和色谱法:affinity chromatography,AC
固定相:stationary phase
化学键合相:chemically bonde phase
封尾、封顶、遮盖:end capping
手性固定相:chiral stationary phase,CSP
恒组成溶剂洗脱:isocraic elution
梯度洗脱:gradient elution
紫外检测器:ultraviolet detector,UVD
荧光检测器:fluorophotomeric detector,FD
电化学检测器:ECD
示差折光检测器:RID
光电二极管检测器:photodiode array detector ,DAD
三维光谱-波谱图:3D-spectrochromatogram
蒸发光散射检测器:evaporative light scattering detector,ELSD
安培检测器:ampere detector,AD
高效毛细管电泳法:high performance capillary electrophoresis,HPCE
淌度:mobility
电泳:electrophoresis
电渗:electroosmosis
动力进样:hydrodynamic injection
电动进样:electrokinetic injection
毛细管区带电泳法:capillary zone electrophoresis,CZE
胶束电动毛细管色谱:micellar electrokinetic capillary chromatography,MECC
毛细管凝胶电泳:capillary gel electrophoresis,CGE
筛分:sieving